Center for Future Chemistry, Kyushu University, 744 Motooka, Fukuoka 819-0395, Japan, Chitose Institute of Science and Technology, 758-65 Bibi, Chitose, Hokkaido 066-8655, Japan, and Koei Chemical Co.

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The change in shape brought about by different intramolecular cyclizations of diastereoisomeric amino propargylic alcohols is quantified using principal moment-of-inertia (PMI) shape analysis.